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HYDRATION



When water is added to cement a chemical process called hydration takes place. Chemicals in the cement chemically react and are transformed into new compounds.


Combined Materials

Transformed Compound

Tricalcium Silicate + WaterTobermorite Gel + Calcium Hydroxide
Dicalcium Silicate + WaterTobermorite Gel + Calcium Hydroxide
Tetracalcium Aluminoferrite + Water + Calcium HydroxideCalcium Aluminoferrite Hydrate
Tetracalcium Aluminate + Water + Calcium HydroxideTetracalcium Aluminate Hydrate
Tetracalcium Aluminate + Water + GypsumCalcium Monosulfoaluminate


The Tobermorite Gel which makes up about 50% of the hydrated cement is the main cementing agent of portland cement however each component has it's own role in the final characteristics of the cement.



Material

Properties

Tricalcium SilicateResponsible for high early strength. It undergoes a final set in a few hours. The chemical reaction with water gives off heat and the rate of hardening is related to this heat of hydration. The majority of it's strength is attained within 7 days
Tricalcium Aluminate Exibits an instant set when combined with water. Primarially responsible for the initial set of the cement. The gypsum controls the time for the initial set. Higher concentrations result in a faster set and an increased resistance to sulfite attack.
Tetracalcium AluminoferriteMaterial hydrates rapidy and develops low strength but does not develop an instant set.


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